Synthesis, Growth and Characterisation of New Organic Crystal: L-Histidinium 5 Sulfo Salicylate for Second Order Nonlinear Optical Applications
Journal: Mechanics, Materials Science & Engineering Journal (Vol.9, No. 2)Publication Date: 2017-04-06
Authors : R. Usha; N. Hema; V. Revathi; Ambika D. Shalini; D. Jayalakshmi;
Page : 244-249
Keywords : Monoclinic; FT-IR; UV and NLO.;
Abstract
L -Histinium 5 Sulfo Salicylate , an organic NLO crystal was grown for the first time by slow evaporation solution technique. Single crystal X ray diffraction analysis reveals that H5S belongs to monoclinic crystal system with non-centro symmetricspace group P21. The determined parameters are a=9.5707(17)A0, b= 19.038(4)A0, c= 8.315(2)A 0,β= 90.711(14) and V= 1514.8(6)A3. FT-IR and FT Raman studies were carried out to identify the functional groups prevent in H5S. Optical absorption study showed a UV cut off wavelength of 304 nm. The mechanical properties of the grown crystal has been analyzed by Vicker micro hardness method. The second harmonic generation was confirmed for LH5SS.
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Last modified: 2017-09-05 19:22:51