Catalytic application of an organosuperbase denderon grafted on mesoporous SBA-15 and related palladium complex in the aerobic oxidation of alcohols
Journal: Iranian Chemical Communication (Vol.2, No. 1)Publication Date: 2014-01-01
Authors : Hojat Veisi; Davood Kordestani; Sami Sajjadifar; Mona Hamelian;
Page : 27-33
Keywords : Organosuperbase; SBA-15; palladium complex; oxidation;
Abstract
An efficient synthetic method for successful synthesis of amine denderon on SBA-15 and related Pd (II) complex has been developed. This modified mesoporous material was characterized by various techniques such as TEM, XRD, atomic absorption spectroscopy, N2 adsorption-desorption, and FT-IR. The catalytic activities of the prepared catalysts were investigated by employing aerobic oxidation of alcohols as model reactions. The yields of the products were in the range from 75% to 92%. The catalyst can be readily recovered and reused at least 5 consecutive cycles without significant leaching and loss its catalytic activity.
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