STUDY OF TYPE OF ELECTROLYTE EFFECT ON PLATINUM ELECTRO-CATALYST PERFORMANCE PREPARED BY CYCLIC VOLTAMMETRY ELECTRODEPOSITION METHOD FOR GLUCOSE OXIDATION REACTION
Journal: MATTER: International Journal of Science and Technology (Vol.1, No. 1)Publication Date: 2015-01-01
Authors : Rasol Abdullah Mirzaie; Behnam Moeini;
Page : 91-102
Keywords : Platinum Electrocatalyst; Cyclic Voltammetry; Fuel Cell; Glucose Oxidation Reaction; Electrodeposition Method.;
Abstract
There are several methods to prepare electro-catalysts for low temperature fuel cells. Platinum is used as a common electro-catalyst for this purpose. Electrodeposition method is applied for preparing platinum on modified carbon paper as electrode directly. Many parameters effect on performance of prepared electrodes. At this work, the effect of type of electrolyte in electrodeposition solution was investigated for making electro-catalyst that is be used as anode in Glucose Alkaline Air Fuel Cell (GAAFC). Cyclic voltammetry ((1.2-0.6) V vs. Ag/AgCl sat. KCl, 100 mV/S) is used as electrodeposition method. Number of CV cycles is varied 10 to 50. Electrodeposition was performed in two precursor solution (0.5 M) containing phosphate and sulfate anions. Platinum concentration in solution was 3 mM. The prepared electro-catalysts were studied for Glucose Oxidation Reaction (GOR) by CV analysis in 0.3 M glucose solution and 0.5 M KOH. Also, Electrochemical Impedance Spectroscopy (EIS) method was used. According our results, the type of anion in electrodeposition solution affects on properties of prepared platinum electro-catalyst for GOR. Optimized condition for number of CV cycles in phosphate and sulfate solutions is 10 and 40 respectively.
Other Latest Articles
- EFFECTIVENESS OF HIDDEN MESSAGES IN ADVERTISEMENTS TOWARDS VIEWERS’ BUYING INTENTION
- Application of ARCS Model and Motivational Design in Engineering Subjects – A Case Study
- NEUTRON ACTIVATION ANALYSIS OF ND-FE-B MAGNET AND DETERMINATION OF THE CONTENT OF ND AFTER OXALATE PRECIPITATION AND PRODUCTION OF ND2O3
- CORRELATION OF STEM STUDENTS’ PERFORMANCE IN THE NATIONAL CAREER ASSESSMENT EXAMINATION AND ACADEMIC SUBJECTS
- Design of Airship for Aerial Surveillance and Communication Using Knowledge Based Engineering
Last modified: 2018-04-26 15:17:55