COORDINATION COMPOUNDS OF CALCIUM ACETATE WITH THIOCARBAMIDE

Homogeneous coordination compounds of calcium acetate with thiocarbamide are synthesized. The structure, identity, thermal behavior, ways of coordination of acetate groups and molecules of carbamide are established. By the methods of oscillatory spectroscopy and the thermal analysis the ways of coordination of organic ligands, environment of the central ion and thermal behavior of the synthesized connections have proved. By comparison of interplanar distances and relative intensities of monohydrate of calcium acetate, thiocarbamide and its coordination compounds of structures Са(СН3СОО)2·2СS(NH2)2 and Са(СН3СОО)2·4СS(NH2)2 it is shown that new coordination compounds differ among themselves and also from initial components, therefore, compounds have an individual crystal lattice.