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THE HYDROSILYLATION OF 3-(HEXEN-5-IN-2-ILOXY) PROPIONITRILE
Journal: Azerbaijan Chemical Journal (Vol.0, No. 1)Publication Date: 2018-03-28
Authors : A.M.Garamanov M.Sh.Gurbanov D.G.Abdullaev N.Kh.Husiev S.N.Allakhverdieva;
Page : 59-64
Keywords : 3-(hexen-5-in-2-iloxy) propionitrile; triorganosilanes; acetylacetonate dicarbonyl rhodium; hydrosilylation; β-isomer; γ-isomer;
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Abstract
The addition reaction of triorganosilanes to 3-(hexen-5-in-2-iloxy) propionitryle in the presence of acetylacetonate dicarbonyl rhodium catalyst proceeds on triple bonds in two directions obtaining of β(52–65%)- and γ(35–48%)-isomers mixture (relatively oxygen atom) and with advantage of β-yield
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Last modified: 2018-12-27 19:43:36