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SYNTHESIS OF NEW AMINOMETHYL AND ORGANYLSULPHIDE DERIVATIVES OF PIPERIDINO-2-HYDROXYPROPANETHIOL-3
Journal: Azerbaijan Chemical Journal (Vol.0, No. 4)Publication Date: 2018-12-25
Authors : V.M.Farzaliyev Sh.R.Aliyev R.F.Mammadova R.M.Babai Q.M.Quliyeva;
Page : 6-12
Keywords : epychlorohydrine; piperidine; formaldehyde; butyl bromide; hydrogen sulphide; aminomethyl derivatives; organylsulphide derivatives;
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Abstract
At interaction of hydrogen sulphide with piperidino-2,3-epoxyprorane there is formed piperidino-2- hydroxypropanthiol-3. The latter reacts by Mannich with formaldehyde and secondary aliphatic and heterocyclic amines, as well with organic halogenide, forming respectively aminomethyl and organyl-sulphide derivatives of piperidino-2-hydroxypropanethiol-3. Composition and structure of synthesized compounds are confirmed by elemental analysis and method NMR
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Last modified: 2019-01-04 16:44:49