COMPLEXES OF URANIUM(VI) WITH DITHIOLPHENOL AND HYDROPHOBIC AMINES IN PHOTOMETRIC ANALYSIS
Journal: Azerbaijan Chemical Journal (Vol.0, No. 2)Publication Date: 2017-06-29
Authors : K.A.Kuliev G.S.Suleymanova;
Page : 64-74
Keywords : uranium; hydrophobic amines; extraction-photometric method; determination;
Abstract
Investigated spectrophotometrically dithiol complexes of uranium with ditiophenols (2,6-dithiol-phenol, 2,6-dithiol-4-methylphenol, 2,6-dithiol-4-ethylphenol, 2,6-dithiol-4-tert-butylphenol), and hydrophobic amines. As hydrophobic amine aniline, N-methylaniline, N, N-dimethylaniline, diphenilguanidine, triphenilguanidine and benzylamine were used. The optimal conditions for the formation and extraction of ionic associates and set the ratio of components in the complex. It has been found that associates formed in a weakly acidic medium (pHopt = 3.6–7.0). The maximum in the absorption spectrum is observed at λ = 435–478 nm. The molar absorption coefficient was (2.68–3.61)•104 l mol-1 cm-1. Based on the data developed by the photometric method of determination of uranium in various objects
Other Latest Articles
- A PROFILE OF CUMENE MODEL AEROBIC OXIDATION IN THE PRESENCE OF 5,10,15,20-TETRAKIS-(2,3,4,5,6-PENTAFLUOROPHENYL)PORPHINE-Fe(III) CHLORIDE
- SYNTHESIS AND CRYSTAL STRUCTURE OF THE FeGaInS4 COMPOUND
- SYNTHESIS OF DERIVATIVES OF N-OXYPHENYLSULPHANYLIDS AND THEIR PROPERTIES
- PARAMAGNETIC PROPERTIES OF COBALT-MOLYBDENUM CATALYSTS OF LIQUID PHASE OXIDATION OF C6–C9 CYCLIC OLEFINS
- INVESTIGATION OF GRANULATION PROCESS AND CALCULATION OF INFLUENCE OF INTENSIFYING ADDITIONS ON STRENGTH OF SUPERPHOSPHATE GRANULES
Last modified: 2019-01-28 19:17:17