SYNTHESIS AND PROPERTIES OF 2-SUBSTITUTED 1,4-ENYNE CHLOROHYDRINS

Journal: Azerbaijan Chemical Journal (Vol.0, No. 3)

Publication Date: 2017-09-27

Authors : A.M.Garamanov M.Sh.Gurbanov A.F.Guliyeva S.N.Allakhverdiyeva;

Page : 43-47

Keywords : 5-methyl hexen-5-yn-2-ol-1; 2; 6-dimethyl hepten-6-in-3-ol-2; 1-chloro-2; 3-epoxy propane; boron trifluoride etherate; dehydrochlorination; epoxy-1; 4-enyne; epoxy-1; 3; 4-trien; hydrosilylation;

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Abstract

By interaction of 2-substituted 1,4-enyne alcohols with 1-chloro-2,3-epoxy propane in the presence of boron trifluoride etherate there have been synthesized 2-substituted 1,4-enyne chlorohydrin by dehydrochlorination of which epoxy-1,4-enynes and epoxy-1,3,4-triens have been prepared. The addition reaction of the methyl diethyl silane to epoxy-1,4-enynes leads to the formation of mixture of silicoorganic epoxy-1,4-dienes

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SYNTHESIS AND PROPERTIES OF 2-SUBSTITUTED 1,4-ENYNE CHLOROHYDRINS

Abstract

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