SYNTHESIS OF OPTICALLY ACTIVE DIETHYL (S)-3-(HYDROXYMETHYL)-3,6-DIHYDROPYRIDAZINE-1,2-DICARBOXYLATE

Journal: Azerbaijan Chemical Journal (Vol.0, No. 4)

Publication Date: 2017-12-25

Authors : F.N.Akhundova M.J.Alves M.M.Qurbanova;

Page : 27-29

Keywords : Diels–Alder reaction; (S)-BINOL chiral catalyst; glycosidase; optical purity;

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Abstract

The optically active diethyl (S)-3-(hydroxymethyl)-3,6-dihydropyridazine-1,2-dicarboxylate were syn-thesized based on asymmetric Diels-Alder reaction in the presence of (S)-BINOL chiral catalyst, the structure was approved by NMR, Mass, Infrared spectroscopies, and specific rotation was determined by AUTOPOL III polarimeter

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SYNTHESIS OF OPTICALLY ACTIVE DIETHYL (S)-3-(HYDROXYMETHYL)-3,6-DIHYDROPYRIDAZINE-1,2-DICARBOXYLATE

Abstract

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