CORRELATION OF FIRE HAZARD CHARACTERISTICS WITH CHEMICAL STRUCTURE. XIX. NITROACETATES
Journal: Pozharovzryvobezopastnost/Fire and Explosion Safety (Vol.24, No. 7)Publication Date: 2015-07-25
Authors : ALEXEEV S. G. Candidate of Chemistry Sciences KOSHELEV A. Yu. Senior Lecturer of Ural State Fire Service Institute of Emercom of Russia BARBIN N. M. Doctor of Technical Sciences SPIRIDONOV M. A. Doctor of Chemical Sciences;
Page : 17-27
Keywords : esters; nitroacetate; flash point; predict; chemoinformatics.;
Abstract
QSPR research in the number of nitroacetates is carried out. It is shown that at the boiling point these compounds exist in mix the keto form and one of the enol forms. It is established that prediction of the boiling and flash points for one of tautomer forms gives unacceptable results. Boiling and flash points of the keto and enol tautomers of nitroacetic esters and isomeric mixtures was calculated by ACDLab 2014 and TEST programs. It was found that flash points of nitroesters can be predicted up to 1–4 degrees using the method of the carbon chain. Empirical equations FP = –0,0833x3 + 1,75x2 – 4,5238x + 361,57 (where x is number of carbon atoms in a molecule) has proposed for the convenience using of this method.
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