Preparation and Study of Waterborne Asphalt Pavement Maintenance Agent
Journal: Materials Science: Materials Review (Vol.1, No. 1)Publication Date: 2017-12-31
Authors : Chunfei Yuan Qinglai Song Ningning Zhao;
Page : 1-9
Keywords : lithium ion battery; doping type cathode material; layered Li [Ni0.8-xCo0.1Mn0.1Mx] O2; coprecipitation method; preparation and performance;
Abstract
The precursor Ni0.76Co0.1Mn0.1 (OH) 2 was prepared by coprecipitation method. The precursor was mixed with Mg (OH) 2 / Zn (NO3) 2 / TiO2 and LiOH.H2O, Li2CO3 to synthesize doped lithium Ion layer positive electrode material Li [Ni0.8-xCo0.1Mn0.1Mx] O2 (x = 0.04). The effects of synthesis conditions on the chemical properties of the composites were discussed. The synthesized samples were prepared by scanning electron microscopy (SEM), thermogravimetry - differential thermal analysis (TG / DTA), X - ray diffraction (XRD) and constant current charge-Testing and characterization. The results show that the crystallinity of Li [Ni0.8-xCo0.1Mn0.1Mx] O2 (x = 0.04) prepared at 900 ℃ for 20 h is good, and it has good layered structure. The properties of the doped elements The results show that the electrochemical performance of the samples with Mg and Zn is good, and the first discharge capacity is 0.1.5mA.h / g and 144.2 mA.h / g (2.8 ~ 4.6 V vs Li + / Li ), The first charge and discharge efficiency was 51.8% and
58.1% respectively, and the capacity retention rates after 8 and 10 cycles were 92.4% and 78.5% respectively. The first discharge capacity of the Ti doped sample was 51.3 mA.h / G, poor electrochemical performance.
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