Synthesis and Structural-chemical Studied of Adduct of Coordination Supramolecular Porous Polymer Hexaaquatribenzene-1,2,4,5-Teacarbonato-tetrairon(iii) with Dipyridyl

An α, α′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acidic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe4 (C6H2 (COO)4)3(dpy)2 (dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.