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Solvent Free Stereoselective Iodoacetoxylation of Alkenes and Glycals Using N-Iodosuccinimide and Acetic Anhydride
Journal: Chemical Methodologies (Vol.3, No. 5)Publication Date: 2019-09-01
Authors : Aleti R. Reddy; Saleem Farooq; Bashir Ahmad Dar;
Page : 599-605
Keywords : N-iodosuccinimide; stereoselective; acetic Anhydride; iodoacetoxylation;
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Abstract
The reactions of glycals with N-iodosuccinimide and acetic anhydride under solvent free conditions provide 2-deoxy-2-iodo-α-mannopyranosyl acetates with good stereoselectivity. The developed process is in accordance with principles of green chemistry and addresses the shortage of such methods for the regioselective iodo acetoxylation of alkenes.
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