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Solvent Free Stereoselective Iodoacetoxylation of Alkenes and Glycals Using N-Iodosuccinimide and Acetic Anhydride

Journal: Chemical Methodologies (Vol.3, No. 6)

Publication Date:

Authors : ; ; ;

Page : 599-605

Keywords : N-iodosuccinimide; stereoselective; acetic Anhydride; iodoacetoxylation;

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Abstract

The reactions of glycals with N-iodosuccinimide and acetic anhydride under solvent free conditions provide 2-deoxy-2-iodo-α-mannopyranosyl acetates with good stereoselectivity. The developed process is in accordance with principles of green chemistry and addresses the shortage of such methods for the regioselective iodo acetoxylation of alkenes.

Last modified: 2020-04-16 01:25:04