Synthesis, Spectroscopic and Biological Studies of Some New Binuclear Thiocyanate Complexes Containing Bidentate Schiff Base Ligands
Journal: International Journal of Science and Research (IJSR) (Vol.7, No. 1)Publication Date: 2018-01-05
Authors : Mouayed Yousif Kadhum; Suhad Rajab Kareem; Sanaa Qasem Badr;
Page : 320-330
Keywords : Schiff base; Binuclear complexes; Thiocyanate; Synthesis; Biological;
Abstract
Two new Schiff bases were synthesized from condensation of 4-nitro benzene diamine with aromatic aldehydes (4-nitro benzaldehyde and 4-hydroxy benzaldehyde). These Schiff bases were reacted with binuclear thiocyanete complexes of MM- (SCN) 4 [M = Co (II), Ni (II), M- = Cd (II)] to produced four new complexes. These compounds were identified by elemental analysis, infrared, Ultraviolet-visible, 1H, 13C-NMR, mass spectra, molar conductance, atomic absorption and magnetic susceptibility. The synthesized Schiff bases were regarded as bidentate ligands and formed complexes of the type LM (NCS) 2M- (SCN) 2. These complexes were non electrolytes and had coordination number equal four. Moreover, these Schiff bases and their complexes were screened for antibacterial and antifungal activity against some microorganisms and compared with standard compounds. It was found that the synthesized compounds had a good antibacterial activity.
Other Latest Articles
- Identification of the Active Ingredients in Methanolic Leaf Extract of Aspilia africana (Pers.) C.D. Adams and their Effects on Ibuprofen Induced Ulcer Model in Wistar Rats
- Smartphone Usage in Higher Learning Institutions in Tanzania: A Case of Institute of Accountancy Arusha
- Role of Dyslipedemia as a Risk Factor in Cerebrovascular Accidents: A Study from Narayana Medical College and Hospital, Nellor
- An Overview on Advances in Cotton Genome and Regulation of Fiber Development
- Morphometry and Histology of Ovaries in Malabari Goats
Last modified: 2021-06-28 18:35:45