Cobalt (III) Complexes of Oxaazamacrocycles Derived from ?-diketones and 1, 12-diamino-4, 9-dioxadodecane
Journal: International Journal of Science and Research (IJSR) (Vol.7, No. 6)Publication Date: 2018-06-05
Authors : Mamta; Mithlesh Agrawal;
Page : 1097-1099
Keywords : cobalt complexes; macrocyclic complexes; magnetic moments; IR spectra; electronic spectra;
Abstract
Co (III) complexes of the type [Co (L) Cl2]Cl (L dioxodiazamacrocyclic with 17-membered ring) were synthesized by the template condensation of Cobalt (III) with a mixture of two different ligands i. e -diketones, such as 2, 4-pentanedione, 1-phenyl-1, 3-butanedione and 1, 3-diphenyl-1, 3-propanedione and dioxadiamines such as 1, 12-diamino-4, 9-dioxadodecane in 111 molar ratio. Different techniques like elemental analysis, FT-IR, FAB masss pectroscopy, and magnetic properties, were characterized to complexes.
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