Synthesis, Spectroscopic Studies and Biologically Active of Uracil and Mixed Ligand with Aluminum (III)
Journal: International Journal of Science and Research (IJSR) (Vol.6, No. 10)Publication Date: 2017-10-05
Authors : Shatha M. H. Obaid; Hanan A.Sh. Al Naemi; Abbas Ali Salih Al-Hamdani;
Page : 1050-1055
Keywords : Mixed ligand complexes; Spectral studies; Biological activities;
Abstract
New complexes of Al (III) such as [Al (Ura) (Phen) (OH2) Cl] Cl.2H2O, [Al (Ura) 2 (OA) (OH2) Cl]. H2O and [Al (Ura) 3Cl3]H2O type, where (Ura) =Uracil, (Phen) = 1, 10-Phenanthroline monohydrate and (OA) = Oxalic acid dihydrate, were prepared. The elemental microanalysis, FT. IR, electronic spectra, and magnetic susceptibility as well as the conductivity measurements are characterized. For isolated three complexes for six coordinated of Al (III) are proposed with molecular formulas that depend on the nature of (Ura), (Phen) and (OA) present. The suggested molecular structure into all complexes for aluminum ion is octahedral geometries. The antibacterial efficacy was examined from metal salt (AlCl3), ligands and metal complexes into the pathogenic bacteria efficacy has been studied
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