SYNTHESIS AND CHARACTERIZATION OF BRIDGED PHTHALOCYANINE & TETRA PYRAZINO PORPHYRAZINE COMPLEXES OF ALUMINUM AND THEIR COPOLYMERJournal: International Journal of Chemical & Petrochemical Technology (IJCPT) (Vol.5, No. 1)
Publication Date: 2014-12-27
Authors : Nazar A. Hussien; Hasan Sabeeh Jabur;
Page : 1-10
Keywords : Bridged Aluminum Phthalocynine and Tetrapyrazino Porphrazine Complexes Abridged Copolymer;
A two types of bridged complexes of Aluminum with two types of ligands phthalocynine and tetrapyrazino Porphrazine were prepared according to an adjusted procedure as in the literatures (1,2) to forms a two complexes Phthalocyanine to separately Aluminum chloride[I] and tetrapyrazino Porphrazine Aluminum chloride[II] then converted separately to phthalocyanato Aluminum hydroxide [III] and tetrapyrazino Porphrazine Aluminum hydroxide[IV]. The hydroxide complexes then converted to the bridged polymeric fluoride complexes [V] and [VI]. Their copolymer [VII] were prepared from the mixture of hydroxide complexes [III] and [IV] of(1:1) ratio to the polymeric fluoride of two ligands. The compounds then characterized by elemental analysis and spectroscopic methods.
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