SYNTHESIS AND CHARACTERIZATION OF BRIDGED PHTHALOCYANINE & TETRA PYRAZINO PORPHYRAZINE COMPLEXES OF ALUMINUM AND THEIR COPOLYMER

A two types of bridged complexes of Aluminum with two types of ligands phthalocynine and tetrapyrazino Porphrazine were prepared according to an adjusted procedure as in the literatures (1,2) to forms a two complexes Phthalocyanine to separately Aluminum chloride[I] and tetrapyrazino Porphrazine Aluminum chloride[II] then converted separately to phthalocyanato Aluminum hydroxide [III] and tetrapyrazino Porphrazine Aluminum hydroxide[IV]. The hydroxide complexes then converted to the bridged polymeric fluoride complexes [V] and [VI]. Their copolymer [VII] were prepared from the mixture of hydroxide complexes [III] and [IV] of(1:1) ratio to the polymeric fluoride of two ligands. The compounds then characterized by elemental analysis and spectroscopic methods.