Conductometric Study of Substitutedthiocarbamidonaphthols in 70% Ethanol?Water Mixture at Different Molar Concentrations at Constant Temperature
Journal: International Journal of Science and Research (IJSR) (Vol.5, No. 1)Publication Date: 2016-01-05
Authors : A. B. Wadekar; D. T. Tayade;
Page : 678-680
Keywords : Thermodynamic parameters; 5-phenylthiocarbamido-1-naphthol PTCN; 5-p-chlorophenylthiocarbamido-1-naphthol p-CPTCN and 5-p-tolylthiocarbamido-1-naphthol p-MPTCN;
Abstract
Recently in this laboratory conductrometric investigation of 5-phenylthiocarbamido-1-naphthol, 5-p-chlorophenylthiocarbamido-1-naphthol and 5-p-tolylthiocarbamido-1-naphthol, have been carried out at different concentrations of solute in 70 % ethanol-water mixture at constant temperature. G, K and values are determined. The thermodynamic parameters viz. H, S and G for the ion pair formation determine from the value of ion association constant at constant temperature. This investigation provided valuable information regarding to solute-solvents, solutesolute and solvent-solvent interaction, effect of various substituents of drugs and effect of dilution from the present conductometric measurements.
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