Synthesis of PQ with its Redox Properties
Journal: International Journal of Science and Research (IJSR) (Vol.5, No. 1)Publication Date: 2016-01-05
Authors : Pratima V. Damre; V. M. Raut;
Page : 927-931
Keywords : PQ; Redox;
Abstract
The thermal, electrochemical, photophysical, and electroluminescent properties of the new polyquinolines varied with the arylene linkage, including p-phenylene, 4, 4'-biphenylene, stilbene, 5, 5'-bithienylene, bis (thienyl)vinylene, and3, 7-phenothiazinylene. The new conjugated polymers combined high glass transition temperature (110-254 ?C) with quasireversible electrochemical reduction from which 2.72-3.00 eV electron affinities were estimated. The optical band gap varied from 2.19 to 2.86 eV whereas the photoluminescence emission maximum varied from blue-green (477 nm) to deep red (646 nm). Some of the new polymers with alternating donoracceptor architecture showed strong intramolecular charge transfer.
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