Studies of Additive Properties of Substituted-dihydropyrimidin-2(1H) One in different Solvent by Refractometrically
Journal: International Journal of Science and Research (IJSR) (Vol.5, No. 6)Publication Date: 2016-06-05
Authors : Y. K. Meshram; S. B. Rewatkar; G. R. Nimbarte; R. R. Dharamkar;
Page : 2142-2148
Keywords : 5-ethoxy carbonyl-4- 4-bromo phenyl -6-methyl-3; 4 dihydropyrimidine-2 1H 0ne; Molar refractivities; molar polarizability constant;
Abstract
Refractive index, molar refractivity and molar polarizability constant of substituted heterocyclic compound such as 5-ethoxy carbonyl-4- (4-nitro phenyl) -6-methyl-3, 4 dihydropyrimidine-2 (1H) 0ne, 5-ethoxy carbonyl-4- (4-bromo-phenyl) -6-methyl-3, 4 dihydropyrimidine-2 (1H) 0ne, have been studied in DMF, THF, Dioxan, Ethanol media at 303 K 0.1C temperature and different concentration (0.625x 10-3to 10.0x 10-3M). The values of molar refraction (Rm) and molar polarizability () constant are found to be decreasedwith decreasing concentration of solute in solvent. Viscosity coefficient (A, B) evaluate by using jone-dole equation. These parameters throw the light on the solute solvent interaction and solute solute interaction
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