DESIGN AND SYNTHESIS OF ZINC(II) COMPLEXES WITH SCHIFF BASE DERIVED FROM 6-AMINOPENICILLANIC ACID AND HETEROCYCLIC ALDEHYDES
Journal: International Journal of Advanced Research (Vol.9, No. 12)Publication Date: 2021-12-14
Authors : Sonal Sengar S.K. Singh; M.K. Gupta;
Page : 965-970
Keywords : Schiff Base Zinc (II) Acetate Heterocyclic Aldehydes Metal Complexes 6-Aminopenicillanic Acid Amino Acids IR UV Elemental Analysis;
Abstract
ReactionofZinc(II)acetatewithSchiffsbasesderivedfromthecondensationofbenzaldehyde or indole-3-carboxyaldehyde with (2S,5R,6R)-6-Amino-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylicacid(6-AminopenicillanicAcid)in1:1molar ratio gave a new series of Zinc(II) complexes. The coordination behavior ofSchiffsbasestowardsZincatomhasbeeninvestigatedbyelementalanalysis,conductancemeasurements,molecularweightdeterminations,IR,UVand1HNMRspectralstudies.
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