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Urea immobilized silica-coated Fe3O4 MNPs as a heterogeneous magnetic nanocatalyst for the synthesis of 2-amino-4H-benzo[b]pyran derivatives

Journal: Asian Journal of Nanoscience and Materials (Vol.5, No. 2)

Publication Date:

Authors : ;

Page : 144-158

Keywords : Fe3O4@SiO2@(CH2)3; Urea Magnetic Nanoparticle Multicomponent reaction Pyran derivatives;

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Abstract

In this work, a novel urea immobilized silica-coated Fe3O4 MNP (Fe3O4@SiO2@(CH2)3-Urea) as a magnetically recoverable and metal-free nanocatalyst was designed and synthesized, and characterized using FT-IR, XRD, FE-SEM, TEM, EDX, and VSM. This system was explored in a three-component reaction to synthesize 2-amino-4H-benzo[b]pyran derivatives of dimedone, malononitrile, and aromatic aldehydes in ethanol at 80 °C. This new method has numerous merits, such as using a green and nontoxic catalyst, excellent yield, shorter reaction time, broad substrate scope, operational simplicity, and functional group compatibility. Moreover, the synthesized nanocatalyst was recovered by a magnetic field, and it was reused eight times without any appreciable change in the catalytic activity.

Last modified: 2022-05-30 13:21:31