Synthesis, Characterization and Thermal Study of Some New Metal Ions Complexes with a New Azo 2-((2-(1H-Indol-2-yl)ethyl)diazinyl)-5-aminophenol
Journal: Journal of Medicinal and Chemical Sciences (Vol.6, No. 1)Publication Date: 2023-01-01
Authors : Myasim Qasim Abdulridha; Abbas Ali Salih Al-Hamdani; Waleed Ali Mahmoud;
Page : 121-131
Keywords : Azo ligand; mass spectroscopy; Spectroscopic studies; Thermal Study; 2-((2-(1H-indol-2-yl)ethyl)diazinyl)-5-aminophenol;
Abstract
This research includes the preparation of a new azo 2-((2-(1H-indol-2-yl)ethyl)diazinyl)-5-aminophenol, in which the diazonium salt of 2(1H– Indole–3yl)- ethylamine reacts with a compound 3-aminophenol, and complexes have been prepared with the ions of Ni (II), Pd(II), Pt(IV), and Au(III). The characteristics of compounds include F.A.A, (C. H .N and O), 1H & 13C-NMR, IR, LC-Mass , UV-Vis spectral, DSC/TGA curve, the measurements of magnetic, and molar conductance. Each complex has an amount of [1:1] [M:L] and does not contain electrolytes. Based on the obtained results, molecular structural and geometry have been octahedral geometry suggest of Pt(IV) complex and tetrahedral of Ni (II)complex, the square planar of both Pd(II) and Au(III) complexes.
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