Synthesis, Spectral Analysis, Stability, Antibacterial, and Antioxidant of Fe(II) Mixed Ligands Complex of Imidazole and 1,10-Phenanthroline
Journal: Journal of Medicinal and Chemical Sciences (Vol.5, No. 7)Publication Date: 2022-12-01
Authors : Salwa Neama Abdoon; Saba S. M. Al-Obaidy; Yahya Fahim Al-Khafaji;
Page : 1231-1241
Keywords : mixed ligands; 1; 10-phenanthroline; Imidazole; Fe(II); Spectrophotometry; antibacterial; Antioxidant;
Abstract
In this study, a new complex consisting of iron metal coordination in a binary oxidation state, synthesized with mixed ligands, which are imidazole and 1,10-phenanthroline. The absorbance measurement at the maximum wavelength of the complex with a concentration of 0.001M was run at 504 nm. For the new complex, the optimum conditions were studied and it was found that it is stable over 3 days at pH 6 at temperature range of (20-80°C). The complex conductivity was 99.7µs/L and it was found that the complex decomposed after 208°C). The formation ratio was 1:2:1 iron: imidazole: 1,10-phenanthroline, respectively. A calibration curve was constructed to determine the limit of detection which was 0.20 mg/L. This study was applied to measure the number of iron ions in the ferrous sulfate tablet and the result was very close to the standard amount of ferrous in tablet sample. The complex formation was detected by using different spectroscopic techniques such as FT-IR and 1HNMR. On the other hand, the antibacterial activity and the antioxidant activity of the complex were studied.
Other Latest Articles
- Immunohistochemical Determination of Estrogen and Progesterone Receptors in Women Breast Cancer Patients
- Positive Dimensions of Mental Health and Personality in a Sample of University
- Detection of the Mycotoxin T2 Produced by Fusarium spp. in Some local Cereal Products and Studying Its Phenotypic Characteristics in Baghdad City
- Psychological and Moral Factors for Elderly in Their Adaptation to Surgical Procedures: A Quasi-Experimental Study
- Identification of Genetic Markers of Drug Resistance and Virulence Factor Gene in Campylobacter Jejuni Isolated From Children in North Iraq
Last modified: 2022-10-09 03:06:05