Cyclic Voltammetry for Interaction between Mercuric Chloride and Diamond Fuchsin (Rosaniline) in 0.05 M NaClO4 Aqueous Solutions at 303 K
Journal: Chemical Methodologies (Vol.7, No. 10)Publication Date: 2023-10-01
Authors : Nawal Daamy Resen; Esam. A. Gomaa; Shereen. E. Salem; Ahmed M. El-Defrawy; Mahmoud Nabil Abd El-Hady;
Page : 736-747
Keywords : Diamond Fuchsin; Complexation stability constant; Functions of thermodynamic; Solvation and kinetic parameters; Complexation;
Abstract
The cyclic voltammetry of different concentrations of mercuric chloride in 0.05 M NaClO4 as a supporting electrolyte was studied in the absence and presence of diamond fuchsin as magneto dye at K using a glassy carbon electrode as the working electrode. The effects of scan speeds (rate) were also studied, and the evaluated data were discussed. Diamond Fuchsin (rosaniline hydrochloride) magneto dye was used as a complexion material. The different solvation, kinetic, and thermodynamic parameters were evaluated from the cyclic voltammograms and found weak interaction between the magneto dye used and mercuric ions. Mercuric chloride can undergo redox reactions and studying its cyclic voltammetry provide insights into its electrochemical properties and have some potential important uses , like, sensor development and toxic estimation in environmental monitoring and electroplating studies. Safety guidelines should be considered by cyclic voltammatery to follow the toxic mercuric ions.The main target is to estimate the qualitative and quantitative concentration of very toxic mercuric ions as safely and fast.
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