ResearchBib Share Your Research, Maximize Your Social Impacts
Sign for Notice Everyday Sign up >> Login

Detection of Iodide Using a Fluorescent Chemosensor Based on Quinaldinium and Imidazole Moieties

Journal: International Journal of Scientific Engineering and Science (Vol.8, No. 8)

Publication Date:

Authors : ; ;

Page : 1-7

Keywords : ;

Source : Download Find it from : Google Scholarexternal

Abstract

—Here, the sensing capability of 2-(2-(1H-imidazol-5-yl)vinyl)-1-ethylquinolin-1-ium iodide (QIM) synthesized by the Knoevenagel reaction, was evaluated with certain anions (F−, Cl−, Br−, I−, CH3COO−, NO3−, HSO4−, and H2PO4−) in solution phase of acetonitrile (MeCN) using fluorescence and absorption spectroscopy techniques. The fluorescence intensity of QIM was substantially quenched upon binding with I− compared to other anions. The detection limit of QIM for I− were calculated as 4.23 μM in MeCN, along with a linear range spanning from 0 μM to 50 μM. Further, the binding mechanism of QIM for detecting I− ion was investigated through Job's plot analysis, and Benesi-Hildebrand study. Job's plots revealed that QIM formed complex with I− in the ratio of 1:1. The binding constant for the QIM-I− complex was determined to be 4.79×105 M−1 by Benesi-Hildebrand equation. Additionally, Stern Volmer quenching constant for the QIM-iodide interaction was determined as 0.0211×106 M-1.

Last modified: 2024-09-22 19:15:14