Intragranular polarization of electronic сharge in metals and her influence on the grain-boundary segregation of admixture elements
Journal: Reporter of the Priazovskyi State Technical University. Section: Technical sciences (Vol.23, No. 1)Publication Date: 2011-12-29
Authors : N.V. Tkachenko; M.A. Ryabikina; K.I. Tkachenko; V.I. Miroshnichenko;
Page : 102-106
Keywords : grain board adsorption; electronegativity; energy of interatomic bond;
Abstract
From the standpoint of electronic theory the features of the formation of grain-border segregation of alloying elements in binary alloys based on iron in the high-temperature region T>0.6 Tm were considered. The values of the binding energy of the atoms of the elements: Mn, Ni, Si, V, Al, Ti and Nb with the grain boundary were calculated and the level of their grain-border segregation СГ/С0 in binary Fe-Me solutions at 1100 K was estimated
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