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Solvent-free Synthesis and Spectral Studies of Some 9-Anthryl-1H-Pyrazolines

Journal: International Journal of Scientific Research in Knowledge (Vol.1, No. 8)

Publication Date:

Authors : ;

Page : 299-307

Keywords : Solvent-free synthesis; 1H-Pyrazolines; IR and NMR spectra; Hammett correlations;

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Abstract

Abstract. Totally ten 3-(9-anthryl)-4,5-dihydro-5-(3-substitutedphenyl)-1H-pyrazolines have been prepared by solvent-free cyclization of 2(E)-1-(substituted phenyl)-3-(9-anthryl)-2-propen-1-ones and hydrazine hydrate in presence of fly-ash:H2SO4 catalyst. These pyrazolines were characterized by their physical constants and spectroscopic data. The assigned infrared νC=N, NH(cm-1), NMR chemical shifts(ppm) of δNH, H4, H4′, H5 and C=N data are correlated with Hammett substituent constants, F and R parameters using regression analysis. From the results of statistical analysis, the effects of substituent on the above group frequencies have been discussed.

Last modified: 2013-09-10 23:29:29