INFLUENCE OF MAGNETIC FIELD UPON REACTIONS IN WATER SOLUTIONS

Journal: BULLETIN OF THE NATIONAL UNIVERSITY OF WATER AND ENVIRONMENTAL ENGINEERING. Technical Sciences (Vol.2, No. 74)

Publication Date: 2016-06-22

Authors : Kochmarskуi V. Z.;

Page : 240-251

Keywords : magnetic effect; spin moments; singlet-triplet evolution of radical pair; radical mechanism of НСО3- ion deprotonization;

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Abstract

The conditions of possible influence of magnetic field upon reactions in solutions are analyzed. Magnetic effects in chemical reactions connected with spin moments may be expected in reactions with radical pairs that have large Δg or with large values super fine interaction energy and quite slow molecular dynamics. Result [2] of singlet-triplet pair evolution in the reactions cell under the influence of field and its effect upon results of reactions with radicals are given. The influence of magnetic field upon CaCO3 crystallization may be explained by formation of transitive complex due to radical mechanism of НСО3- → СО3∙ - + Н∙ ion deprotonization.

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INFLUENCE OF MAGNETIC FIELD UPON REACTIONS IN WATER SOLUTIONS

Abstract

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