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Thermodynamic Approach for Oxidation of p-Chloro Benzoic Acid Hydrazide by Thallium (III) in Acidic Medium - A Kinetic and Mechanistic Study

Journal: International Journal of Science and Research (IJSR) (Vol.3, No. 5)

Publication Date:

Authors : ; ;

Page : 1857-1859

Keywords : kinetics; Thallium(III); Oxidation.;

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"The kinetics of oxidation of benzoic and p-Chloro benzoic acid hydrazide by Thaliium(III) in a mixture of perchloric and hydrochloric acid medium at a constant ionic strength has been planned to study iodometrically. TlIII + Hydrazide Complex Kc Complex ? TlI + Intermediate kl TlIII+Intermediate ? TlI + Products fast The increase in [H+] and [Cl-] decreases the rate of the reaction. The activation parameters were also determined and a mechanism is predicted."

Last modified: 2014-07-03 19:08:54