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CATALYTIC HYDROSILYLATION OF 5-METHYLHEXENE-5-YN-2-OL-1

Journal: Azerbaijan Chemical Journal (Vol.0, No. 2)

Publication Date:

Authors : ;

Page : 62-66

Keywords : 5-methylhexene-5-yn-2-ol-1; trialkylsilane; benzene; hydrosilylation; 1-chloro-2; 3-epoxy-pro¬pane; boric acid; acrylonitrile;

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Abstract

The addition of trialkylsilanes to 5-methylhexene-5-yn-2-ol-1 in the presence of H2PtCl6.6H2O proceeds via a triple bond, but with an advantageous yield (80-90%) of the β-isomer (relatively oxygen atom). The reaction of organosilicon 1,4-diene alcohol with 1-chloro-2,3-epoxypropane, boric acid and acrylonitrile produced corresponding chlorohydrin, tris-borate and nitrile

Last modified: 2019-07-01 21:35:31