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Efficient Synthesis of Bis(3-Methylphenyl)Sulfoxide Aza Macrocycles from a Bis(3-Methylphenyl)Sulfoxide Diester and Diamine Derivatives

Journal: Journal of Applied Organometallic Chemistry (Vol.2, No. 3)

Publication Date:

Authors : ; ; ;

Page : 158-164

Keywords : Bis(3-methylphenyl)sulfoxide aza macrocycles; bis(3-methylphenyl)sulfoxide diester; aliphathic diamines; methyl chloroacetate; Complexation;

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Some bis(3-methylphenyl)sulfoxide aza macrocycles (3–8) were synthesized in high yields based on the conventional methods of the reaction of corresponding bis(3-methylphenyl)sulfoxide diester and diamines in refluxing methanol. Bis(3-methylphenyl)sulfoxide diester was synthesized from the reaction of 2-[(2-hydroxy-5-methylphenyl)sulfinyl]-4-methylphenol and methyl chloroacetate. The structures of these compounds were confirmed using IR, 1H NMR, 13C NMR and Mass spectroscopy.

Last modified: 2023-03-15 14:51:38