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Synthesis and Physiochemical studies of some metal complexes of Ti(III) with Phthalimide or Succinimide

Journal: International Journal of Engineering and Technical Research ( (Vol.1, No. 10)

Publication Date:

Authors : ; ; ; ;

Page : 9-12

Keywords : erpublication; IJETR;

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Mixed ligand complexes of Ti(III) with phthalimide or succinimide as primary ligands and amino acids as secondary ligands have been synthesized. The general formula of these complexes are follows: K[Ti(L)2 (L′)2 ] where L= phthalimide; C8H4O2N(1-3), succinimide; C4H4O2N(4-6); and L′ =amino acids. The complexes were prepared in the solid form and characterization by elemental analysis, conductivity, magnetic moment measurement, IR, 1H-NMR, 13C-NMR, FAB+ mass and electronic spectroscopic studies. The value of 10 Dq was found to be 12250-13965 cm-1 for all complexes. The value of B, β and ligand field stabilization energy have also been calculated from the bands obtained in the electronic spectra of the complexes . Electronic and other measurements confirmed their octahedral structure.

Last modified: 2017-06-25 16:09:44