Synthesis and Physiochemical studies of some metal complexes of Ti(III) with Phthalimide or SuccinimideJournal: International Journal of Engineering and Technical Research (www.erpublication.org) (Vol.1, No. 10)
Publication Date: 2013-12-30
Authors : Anwar Hossain; SK AL Zaheri Mahmud; Chanmiya Sheikh; M. Saidul Islam;
Page : 9-12
Keywords : erpublication; IJETR;
Mixed ligand complexes of Ti(III) with phthalimide or succinimide as primary ligands and amino acids as secondary ligands have been synthesized. The general formula of these complexes are follows: K[Ti(L)2 (L′)2 ] where L= phthalimide; C8H4O2N(1-3), succinimide; C4H4O2N(4-6); and L′ =amino acids. The complexes were prepared in the solid form and characterization by elemental analysis, conductivity, magnetic moment measurement, IR, 1H-NMR, 13C-NMR, FAB+ mass and electronic spectroscopic studies. The value of 10 Dq was found to be 12250-13965 cm-1 for all complexes. The value of B, β and ligand field stabilization energy have also been calculated from the bands obtained in the electronic spectra of the complexes . Electronic and other measurements confirmed their octahedral structure.
Other Latest Articles
Last modified: 2017-06-25 16:09:44