Production of oxide films on alumosilicate microspheres by thermolysis of methansulfonate complexes of zirconium(iv) and titanium(iv)

Annotation. Purpose. Forming of oxide films is from the methanesulfonic complexes of Zirconium(IV) and Titanium(IV) on the surface of alumosilicate microspheres. Methodology. Deposition of films was carried out by of impregnation method of alumosilicate microspheres by water or hydroalcoholic solutions of methanesulfonic Zirconium(IV) (ZrO(SO3CH3)2∙4H2O) and methanesulfonic Titanium(IV) (TiO(SO3CH3)2∙nH2O) with the further drying and calcination at the temperature of 500оС. Research of the got tapes was conducted by methods thermal and X-Ray analyses and light microscopy. Finding. It is set that the methanesulfonic complexes of Zirconium(IV) of Titan(IV) are actively adsorbed on the surface of alumosilicate microspheres and in the process of their further thermooxidizing form the superficial thin-films of oxides of zirconium and titan. Scientific novelty. First experimental formation of nanosize films of dioxide of Zirconium(IV) and Titan(IV) is set on the surface of alumosilicate microspheres by thermolysis of methanesulfonic complexes to Zirconium(IV). and Titanium(IV). Practical value. Methanesulfonic complexes of Zirconium(IV) and Titanium(IV) are perspective precursors for the receipt of nanofilms of Zirconium oxide and to the titania oxide on different transmitters, that creates preconditions for development of new functional and construction materials of the different technological setting.