Thermodynamic and Adsorption Behavior of eco-Friendly Purine Derivatives on the Corrosion of Carbon Steel in 1 M HCl
Journal: International Journal of Science and Research (IJSR) (Vol.3, No. 5)Publication Date: 2014-05-15
Authors : Ahmed A. Farag; Khalid Zakaria;
Page : 1092-1099
Keywords : Carbon steel; Acid corrosion; EIS; Polarization; SEM;
Abstract
The behavior of carbon steel in 1.0 mol dm-3 HCl in the presence of novel purine inhibitors namely 1H-pyrazolo[3,4-d]pyrimidin-4(2H)-one (PPO) and 6-[(1-methyl-4-nitro-5-imidazolyl)sulfanyl]purine (ISP) in the concentration range (1×10−4 − 5×10−3 mol dm−3) was studied using weight loss, open circuit potential, potentiodynamic polarization electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) techniques. Potentiodynamic polarization shows that PPO and ISP act as mixed-type inhibitors. The values of the activation energy, equilibrium constant, free energy of adsorption, activation enthalpy and activation entropy were discussed. The adsorption of inhibitors on metal followed Langmuir’s adsorption isotherm. The values of suggest the chemical adsorption of PPO and ISP on carbon steel surface.
Other Latest Articles
- Influence of Nonionic Surfactant on the Carbon Steel Corrosion in Hydrochloric Acid Solution
- A Comprehensive Analysis of Existing Load Balancing Algorithms in Cloud Network
- Applications of Total Quality Management in Indian Airline Industry
- Effect of Reflection Property on Microwave Absorbing Materials - A Review
- A Semi-Distributed Load Balancing Algorithm Using Clustered Approach?
Last modified: 2014-07-02 19:53:02