SYNTHESIS OF MONO-, BI- AND TRINUCLEAR CARBINOL DERIVATIVES OF FERROCENE, DEVELOPMENT OF TECHNOLOGIES OBTAINING OF THIN COVERINGS OF PHOTOCOMPOSITES WITH POLYMER MATRIXES AND STUDY OF SOME ELECTROPHYSICAL PROPERTIES
Journal: Azerbaijan Chemical Journal (Vol.0, No. 4)Publication Date: 2017-12-25
Authors : G.Z.Suleymanov M.A.Gurbanov A.Kh.Akbarov Z.M.Mammadova A.F.Gochuyeva;
Page : 48-54
Keywords : mono-; bi-; trinuclear ferrocenylcarbinols [C5H5FeC5H4]nC–OH (n=1; 2; 3); polymer pho¬to-composite materials; photo quenching effect;
Abstract
Synthesis technology of mono-, bi-, trinuclear carbinol derivatives of ferrocene [C5H5FeC5H4]nC–OH (n=1, 2, 3) was developed and thin coverings of photocomposite materials with polymer matrixes were produced. Considering the dependence of photo quenching efficiency of photocomposite ferrocene–polymer depends on the amount of ferrocene, in the work the experimental results of the dependence in composition samples on a number of nuclei of ferrocene were presented, as well as the reasons of electroconductivity of photo quenching in samples based on mono- and multinuclear carbinols of polymer–ferrocene were determined and the mechanism of photo quenching effect was proposed.
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