PHASEFORMATION IN THE SYSTEM InAs2S3Se–InAs2Se3S AND PROPERTIES OF OBTAINED PHASES
Journal: Azerbaijan Chemical Journal (Vol.0, No. 2)Publication Date: 2019-06-28
Authors : I.I.Aliyev O.M.Aliyev R.S.Mahammadrahimova;
Page : 44-47
Keywords : system; quasi–binary; solid solution; syngony; microhardness;
Abstract
Compound InAs2S2Se2 was found during studying the system InAs2S3Se–InAs2Se3S. It was established that the compound InAs2S2Se2 melts congruently at 615 K. crystallizes in tetragonal syngony with lattice parameters: а=9.22±0.01, с=5.81±0.002 Å; Z=3. Coordinates of eutectic points: 40 mol % InAs2Se3S, Т=548 K and 60 mol % InAs2Se3S, Т=580 K. Narrow solid solution ranges are formed on the basis of primary components. Solid solutions based on InAs2S3Se at room temperature reach up to 5 mol %, but on the basis of InAs2Se3S – up to10 mol %
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