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CATALYTIC HYDROSILYLATION OF 5-METHYLHEXENE-5-YN-2-OL-1
Journal: Azerbaijan Chemical Journal (Vol.0, No. 2)Publication Date: 2019-06-28
Authors : A.M.Garamanov N.Kh.Gusiev D.G.Abdullaev O.B.Abdiev M.Sh.Gurbanov S.A.Rzaeva;
Page : 62-66
Keywords : 5-methylhexene-5-yn-2-ol-1; trialkylsilane; benzene; hydrosilylation; 1-chloro-2; 3-epoxy-pro¬pane; boric acid; acrylonitrile;
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Abstract
The addition of trialkylsilanes to 5-methylhexene-5-yn-2-ol-1 in the presence of H2PtCl6.6H2O proceeds via a triple bond, but with an advantageous yield (80-90%) of the β-isomer (relatively oxygen atom). The reaction of organosilicon 1,4-diene alcohol with 1-chloro-2,3-epoxypropane, boric acid and acrylonitrile produced corresponding chlorohydrin, tris-borate and nitrile
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Last modified: 2019-07-01 21:35:31