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N,N,N',N'-tetramethylethylene-diaminium-N,N'-disulfonic acid chloride as a highly effective catalyst for the synthesis of 4H-pyrano[2, 3-c]pyrazoles, α-carbamatoalkyl-β-naphthols and α-amidoalkyl-β-naphthols

Journal: Asian Journal of Green Chemistry (Vol.4, No. 2)

Publication Date:

Authors : ; ; ; ; ; ; ; ;

Page : 173-182

Keywords : N; N'; N'-Tetramethylethylene-diaminium-N; N'-disulfonic acid chloride {[TMEDSA][Cl]2} Sulfonic acid-functionalized ionic liquid 4H-Pyrano[2; 3-c]pyrazole α-Carbamatoalkyl-β-naphthol α-Amidoalkyl-β-naphthol;

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Abstract

In this work, N,N,N',N'-tetramethylethylene-diaminium-N,N'-disulfonic acid chloride {[TMEDSA][Cl]2} has been utilized as a highly effective catalyst in order to promote the following organic transformations under green, solvent-free and mild conditions: (i) the synthesis of 4H-pyrano[2, 3-c]pyrazoles from aromatic aldehydes, 3-methyl-1-phenyl-2-pyrazolin-5-one and malononitrile, (ii) the preparation of α-carbamatoalkyl-β-naphthols from arylaldehydes, β-naphthol and alkyl carbamates, and (iii) the production of α-amidoalkyl-β-naphthols from arylaldehydes, β-naphthol and amides.

Last modified: 2020-02-08 04:48:53