ECOLOGICAL ASPECTS OF PHENOL DECOMPOSITION IN THE BASIS OF PHOTOLYSIS REACTIONS
Journal: Azerbaijan Chemical Journal (Vol.0, No. 1)Publication Date: 2020-03-24
Authors : E.M.Gadirova;
Page : 71-76
Keywords : UV -radiation; methyl-3-aminocrotonate; phenol; degradation; TiO2 nanoparticles;
Abstract
For the first time, there was carried out photochemical dissociation of phenol in the presence of TiO2 na-noparticles and methyl-3-aminocrotonate. It is established that 80% of phenol was decomposed. The process lasted for two hours. Results are confirmed by the mass-chromatography. The nanocrystalline TiO2 powders were composed of rutile form TiO2 obtained by XRD. The size of nanoparticles was ex-amined by transmission electron microscopy analysis and is about 10–20 nm, general surface area of nanoparticles made up 159.6 m2/g. The photolysis process was carried out at UV radiation and the coefficient dependence on the wavelength was determined by the Varian device
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