Analysis of C-H...F and O-H...N Intermolecular Interactions Involving Fluorine in A New Mixed Composite Material 5- Fluoro salicylaldehyde -Aniline
Journal: International Journal of Science and Research (IJSR) (Vol.4, No. 1)Publication Date: 2015-01-05
Authors : R.Ida Malarselvi; C. Ramachandra Raja; Priscilla.R;
Page : 706-711
Keywords : Intermolecular interactions; second sphere interactions; 5FS-A composite material;
Abstract
We synthesized a new composite material containing 5-Fluoro salicylaldehyde with Aniline in CCl4 medium. A detailed packing analysis has been undertaken to delineate the role of C-H. F interactions amid other hetroatom interactions. The composite material have been characterized by elemental analyses, Spectroscopic studies (IR, multinuclear NMR) and Physico-chemical behavioural studies. The complex structure is calculated by the spectral analyses as non-centro symmetric, bent, complex in nature, containing five interacting nuclei A BB MM system. The composite material was stabilized by a variety of hydrogen bonding interactions (i. e) O-H. . N and C-HF. Furthermore, packing analyses reveal that C-HF interactions can manifest even in the presence of a large number of hetroatom interactions. To reinforce the ideas investigated and to reveal the validity of the proposed models, experimental results are discussed with the outputs through the Software MATLAB7.0.
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