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Four-Component Synthesis of Polyhydroquinolines via Unsymmetrical Hantzsch Reaction Employing Cu-IRMOF-3 as a Robust Heterogeneous Catalyst

Journal: Chemical Methodologies (Vol.6, No. 9)

Publication Date:

Authors : ; ;

Page : 639-648

Keywords : Metal-organic Frameworks; Polyhydroquinoline; IRMOF-3; Unsymmetrical Hantzsch reaction;

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Abstract

In this report, an IRMOF-3 was synthesized via a solvothermal method and then used as support for stabilizing Cu(II) ions. Characterization methods such as FT-IR, XRD, SEM, and BET were employed to analyze produced Cu@IRMOF-3, demonstrating that the suggested catalyst effectively conserved its structure throughout the synthesis processes. The FT-IR results indicate that the presence of the -NH2 group in the structure of the MOF helped stabilize the Cu(II) ions. The manufactured catalyst was used to prepare polyhydroquinoline derivatives which showed superior results.

Last modified: 2022-07-10 18:03:13