СПЕКТРОСКОПИЧЕСКОЕ ИССЛЕДОВАНИЕ КОМПЛЕКСООБРАЗОВАНИЯ ТИТАНА С 2,6-ДИТИОЛ-4-МЕТИЛФЕНОЛОМ И АМИНОФЕНОЛАМИ

By the methods spectrophotometric methods was investigated complex formation of titan (IV) with 2,6-ditiol-4- methylphenol (DTMPh) and aminophenols (AP). Titan (IV) form with DTMPh colored insoluble in inpolar organic solvents. Experiments with electromigratory in U-form tube and anion exchange on EDE-10 P anionit showed anion character of compounds. When hydrophobic amins were introduced in systems extraction of their compounds in form of different ligand complexes to organic phase is observed. As aminophenols were used 2-(N, N?dimethylaminophenol, 2-(N, N? dimethylaminophenol and 2-(N, N?dimethylaminophenol. It was established, that mixedligand complex were formed in weak acidic medium (рНоpт=1,7-3,4). Maximal light absorption of complexes observe at 430-435 nm. Relative molar absorption coefficients are vacillated with the interval (2,55-2,74)?104.