INFLUENSE OF SULFURDERIVATION PHENOLS AND AMINES ON DECOMPOZITION OF HYDROPEROXIDES
Journal: Science and world (Vol.3, No. 9)Publication Date: 2014-05-25
Authors : Kashkay A.M.; Litvishkov Y.N.;
Page : 102-108
Keywords : polifenolsulfid; ditioltion hydroperoxide; cumene hydroperoxide; n-decyl; autocatalytic process; peroxy stoichiometric reaction.;
Abstract
Inluense of sulfuric derivatines polyhhenolsulfides (PFS) and dithiolthion cumyl (HPC) and n-decyl on decomposition of hydroperoxides was studied. Decompozition of cumyl hydroperoxides(CHP) with tht presense oof polyphenolsulfides (PPS) is a complex multistage autocatalytic process and as a result of the process an effective catalyst for decomposition is formed. During decompozition of CHP üith the presence of peroxy radicals deactivation of PPS as a catalyst üas determind. Dithiolthion decomposes CHP catalitically, stechiometricric reaction with n-decyl is observed.
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